Pseudo-Bimolecular [2+2] Cycloaddition Studied by Time-Resolved Photoelectron Spectroscopy
نویسندگان
چکیده
منابع مشابه
Pseudo-bimolecular [2+2] cycloaddition studied by time-resolved photoelectron spectroscopy.
The first study of pseudo-bimolecular cycloaddition reaction dynamics in the gas phase is presented. We used femtosecond time-resolved photoelectron spectroscopy (TRPES) to study the [2+2] photocycloaddition in the model system pseudo-gem-divinyl[2.2]paracyclophane. From X-ray crystal diffraction measurements we found that the ground-state molecule can exist in two conformers; a reactive one in...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2011
ISSN: 0947-6539
DOI: 10.1002/chem.201002928